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N2 Laser-excited luminescence of antiferromagnetically coupled trinuclear chromium(III) complexes (1980)

Morita, Makoto ; Kato, Yoshiaki

New York, NY : Wiley-Blackwell

International Journal of Quantum Chemistry 18 (1980), S. 625-631

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ISSN: 0020-7608

Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Exchange interaction parameters in several trinuclear chromium(III) complexes [Cr3O(R-COO)6(H2O)3]X·nH2O (R = CH3, C2H5) are determined in the study of luminescence, time-resolved luminescence (TRS), and decay time measurements over the temperature range 4-100°K. The presence of four inequivalent trinuclear clusters and a luminescence anomaly at 25 and 55°K are observed in the basic chromium(III) acetate prisms. Magnetic anomalies reported earlier should be attributed to the distortion and disordering of the hydrogen-bonded channels in crystals at low temperatures.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/qua.560180237

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