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Molecular Recognition of NADP(H) and ATP by Macrocyclic Polyamines Bearing Acridine Groups (1997)

Fenniri, Hicham ; Hosseini, Mir Wais ; Lehn, Jean-Marie

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 80 (1997), S. 786-803

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The macrocyclic polyamine-based receptor BA bearing two acridine units makes use of combined electrostatic and stacking interactions for the binding of nucleotide polyphosphates and for the recognition of ATP and of NADPH (ka 〉 3 · 108 M), with a high selectivity for NADPH vs. NADP (ca. 103) and NAD(H) (〉 106). The binding properties of this receptor towards a variety of substrates led to its in vitro application as a fluorescent probe for ATP. BA also interacts strongly with nucleic acids as shown by spectrophotometric, spectrofluorimetic, and electrophoretic mobility methods.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19970800314

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