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Catalytic C(1), C(2)-Bond Cleavage of Long-Chain Aliphatic Alcohols and ω-Phenylalkyl Alcohols (1977)

Baiker, Alfons ; Richarz, Werner

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 60 (1977), S. 2958-2963

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A catalytic one step procedure for the C(1), C(2)-bond cleavage of long-chain aliphatic alcohols and ω-phenyl alcohols has been investigated, using as examples decanol, dodecanol, hexadecanol, benzyl alcohol, 2-phenylethanol and 3-phenyl-propanol. The reactions, which were carried out in a continuous flow tubular reactor using a Ni/Cu catalyst, showed good activity and selectivity with respect to the cleavage products. On the basis of the experimental studies a reaction scheme for the heterogeneous catalytic C(1), C(2)-bond cleavage of the alcohols is suggested.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19770600848

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