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23Na-NMR. Linewidths in Binary Mixtures of Oxygenated Solvents (1976)

Detellier, Christian ; Laszlo, Pierre

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 59 (1976), S. 1346-1351

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The inference of single bicyclic intermediates in the competition of diglyme (or triglyme)For abbreviations see the table of [1]. with tetrahydrofurfuryl alcohol is confirmed by analysis of the linewidths. The dissymetric bicyclic species are characterized by linewidths increased markedly with respect to the pure solvents, without an accompanying change in the 23Na chemical shift. Conversely, the competition of glyme with the same alcohol involves three equi-probable intermediates; that of tetrahydrofuran (or tetrahydropyran) is of greater conceptual complexity.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19760590437

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