ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
For picric acid and 2,4,6-trinitroresorcinol the following thermodynamic acidity constants at 25° are determined by spectrophotometric measurements in dilute aqueous perchloric acid or acetate buffer: pK0 =0,373 (±0,010) (picric acid), and pK10 =0,06 (±0,015), pK20 =4,227 (±0,010) (2,4,6-trinitroresorcinol). The data are discussed from the point of view of substituent effects.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19640470119