ISSN:
0941-1216
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Distribution Properties of Benzene Derivatives. III. On the Kinetics of the Diffusion-controlled Distribution of Mono- and Disubstituted Benzene Derivatives in the System n-Octanol/WaterThe kinetics of the diffusion-controlled distribution of 22 mono- and disubstituted benzenes in the solvent system n-octanol/water were investigated spectrophotometrically in the UV-VIS range at various temperatures between 288 and 333 K.The first-order rate constants k1 and k2 and the activation parameters were determined graphically.In this way, an interesting deviation from theory could be observed in the temperature range from 300 up to 308 K, which is discussed on the basis of known anomalies of water at the interface.Studies on relationships between rate constants (lg k1, lgk2) and hydrophobicity (lgP) show a nearly constancy of k1, while the rate of transport from the organic to the aqueous phase (k2) strongly depends on hydrophobicity described by lgP.The calculated regression equations correspond to analogous relationships found for mechanically influenced distributions and can therefore be explained by the same kinetical model.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19933350310
