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Synthese fluorhaltiger PolycarbosilaneHerrn Professor Alois Haas zum 60. Geburtstag gewidmet (1992)

Habel, Wolfgang ; Mayer, Lutz ; Sartori, Peter

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 334 (1992), S. 327-332

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ISSN: 0941-1216

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Synthesis of Fluorinated PolycarbosilanesFluorine containing polycarbosilanes could be obtained by the reaction of the completely halogenated compounds poly(dichlorocarbosilane) and poly(dibromocarbosilane) with fluorinating agents like ZnF2, KHF2, SbF3, NH4F, NH4HF2, HF and LiF.The most successfully applied fluorinating agent was LiF. The substitution reaction of LiF yielded a fluoropolycarbosilane with a fluorine content of more than 30 weight per cent.This fluorinated compound D-PFC with a high hydrolitic resistance was analytically and spectroscopically investigated.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prac.19923340406

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