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  • 1
    Electronic Resource
    Electronic Resource
    Amphiphilic carbohydrate-based mesogens, V. Mesogenic 1-O-alkyl-D-glucitols from alkyl D-glucopyranosides (1990)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1990 (1990), S. 811-813 
    Details
    ISSN: 0170-2041
    Keywords: Liquid crystals ; 1-O-Alkyl-D-glucitols ; Glycoside hydroboration ; Carbohydrates ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The endocyclic acetal bonds of alkyl D-glucopyranosides (hexyl to decyl, 1a - e) are regioselectively hydroborated with ethyldiboranes(6) in the presence of 9-methylsulfonyloxy-9-borabicyclo[3.3.1]nonane (MSBBN) after conversion to their 2,3,4,6-tetra-O-diethylboryl derivatives 2a - e. Subsequent deboronations give the mesogenic 1-O-alkyl-D-glucitols 3a - e.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.1990199001150
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