ISSN:
0170-2041
Schlagwort(e):
Amination
;
Nitroisoquinolines
;
Calculations, FMO
;
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
5- and 8-Nitroisoquinoline and some of their derivatives are aminated in a liquid ammonia solution of potassium permanganate to yield the corresponding 6- and 7-amino compounds. From 5,7-dinitroisoquinoline the 6,8-diamino derivative is obtained; 1-nitroisoquinoline has been found to be unreactive. FMO calculations made for a few nitroisoquinolines confirm the experimentally observed regioselectivity of the amination.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/jlac.1990199001124