ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Syntheses of Peptide Alkaloids, 11. - Amino Acids and Peptides, 51. - Dehydroamino Acids, 19. - Total Synthesis of Hexaacetylcelenamide AThe total synthesis of the linear peptide alkaloid hexaacetylcelenamide A (7) is described. Key steps are two condensation reactions with α-dialkylphosphoryl amino acid derivatives 10 to obtain the dehydroamino acid and dehydro peptide derivatives 14 and 17, respectively.
Notes:
Es wird die Totalsynthese des linearen Peptidalkaloids Hexaacetylcelenamid A (7) beschrieben. Schlüsselreaktionen sind zwei Kondensationen mit α-(Dialkylphoshoryl)aminosäurederivaten 10 zum Aufbau der Dehydroaminosäure- und Dehydropeptidderivate 14 bzw. 17.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198519850915
