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1-Metalla-1,3,5-hexatrienes and Related Compounds (2000)

Aumann, Rudolf

Weinheim : Wiley-Blackwell

Liebigs Annalen 2000 (2000), S. 17-31

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ISSN: 1434-193X

Keywords: Carbene complexes ; Chromium ; Tungsten ; Hexatrienes ; Azahexatrienes ; Transmetalation ; Alkynes ; Polyenes ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: ---The term 1-metalla-1,3,5-hexatriene applies to a huge number of transition metal carbene complexes which contain a 1,3-butadien-1-yl side chain attached to the carbene carbon atom. Compounds of this type were found to play a crucial role as key intermediates and have also been utilized as stoichiometric reagents in a number of high-yielding transformations, which may successfully be applied to organic syntheses. Typical reaction pathways, structural features, and preparations of such compounds (with focus on M = Cr and W) have been summarized.

Type of Medium: Electronic Resource

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