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Mild Synthesis of Protected α-D-Glycosyl Iodides (1999)

Caputo, Romualdo ; Kunz, Horst ; Mastroianni, Domenico ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 3147-3150

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ISSN: 1434-193X

Keywords: Glycosyl iodides ; Triphenylphosphane-iodine complex ; Carbohydrates ; Glycosides ; Polymer bound reagents ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: α-D-Glycosyl iodides are stereoselectively obtained by iodine replacement of the free anomeric hydroxyl group of fully protected sugars treated with a polymer bound triarylphosphane-iodine complex and imidazole. High yields and mild conditions, compatible with all the common protecting groups used in carbohydrate chemistry, characterize the conversion.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

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