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Synthesis and Structure of the First Fullerene Complex of Titanium Cp2Ti(η2-C60) (1999)

Burlakov, V. V. ; Usatov, A. V. ; Lyssenko, K. A. ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 1855-1857

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ISSN: 1434-1948

Keywords: Fullerenes ; Titanium ; Complexes ; X-ray analysis ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The first fullerene complex of titanium Cp2Ti(η2-C60) has been synthesized by reaction of the bis(trimethylsilyl)-acetylene complex of titanocene Cp2Ti(η2-Me3SiC2SiMe3) with an equimolar amount of fullerene-60 in toluene at room temperature under argon. An X-ray diffraction study of the complex has shown that it has the structure of a titanacyclopropane derivative.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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