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Te…Te Interlayer Interactions, Te → Metal Electron Transfer and Electrical Conductivity in the MM′Te5 Phases (M = Nb, M′ = Ni, Pd; M = Ta, M′ = Ni, Pt) (1999)

Alemany, Pere ; Canadell, Enric

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1999 (1999), S. 1701-1706

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ISSN: 1434-1948

Keywords: Ternary Tellurides ; Conductivity ; Electronic structure ; Layered compounds ; Low-dimensional metals ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The layered ternary tellurides NbNiTe5, TaNiTe5, TaPtTe5 and NbPdTe5 are all metallic, but the conductivity of the latter is between one and two orders of magnitude smaller. A tight binding study of the electronic structure of these phases suggests that the large conductivity difference results from the different Te···Te interlayer interactions and the Te → M (M = Nb, Ta) electron transfer that they induce.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

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