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Five- and Six-Coordinate Nitrogen in Azaborane Clusters (1998)

Paetzold, Peter

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 143-153

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ISSN: 1434-1948

Keywords: Azaboranes ; Six-coordinate nitrogen ; Deltahedral clusters ; Cluster opening ; Cluster closure ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In the majority of known azaboranes NaBbHc and their derivatives, the coordination number of the nitrogen atoms within the cluster does not exceed the classical values of 3 or 4. In the azaboranes closo-NB9H10, nido-NB10H13, and closo-NB11H12 and in their derivatives, however, the nitrogen atoms are 5- or 6-coordinate and thus represent a novel bonding situation. The synthesis, structure, and reactivity of these azaboranes are reviewed in this article.

Type of Medium: Electronic Resource

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