ISSN:
0075-4617
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Reactions of Phenylaminoaluminium, III1). - Reactions of (N-Alkylphenylamino)aluminiums with AldiminesIt is shown that, like dialkyl(N,N-diphenylamino)aluminiums 1, the (N-alkylphenylamino)-aluminiums of type 2 react with aldimines by addition of the C—N group to the ortho-H of the phenylamino group. The N-benzhydrylidenanilines 4 (Table 1) are formed, which now are easily preparable in yields of up to 65%.
Notes:
Es wird gezeigt, daß analog den Dialkyl(N,N-diphenylamino)aluminium 1 auch (N-Alkyl-phenylamino)aluminium des Typs 2 mit Aldiminen durch Anlagerung der C=N-Gruppe an den ortho-Wasserstoff der Phenylaminogruppe reagieren. Dabei entstehen die N-Benzhydrylidenaniline 4 (Tabelle l), die somit in Ausbeuten bis 65% leicht zugänglich werden.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.197419740204
