ISSN:
0075-4617
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Aliphatic α-Substituted Nitroso Compounds, I. Chemistry and Stereochemistry of α-Substituted 3-Nitrosomenthanes3-Nitroso-3-halo- or 3-nitroso-3-acyloxymenthanes 2 are prepared. Their isomerisation to the diastereoisomeric 6 and the substitution reactions of the halogen derivatives are investigated. UV- and NMR-spectra as well as CD-curves of the nitrosomenthanes 2 and 6 are used to obtain information about the stereochemistry of these compounds (tables 1-4, figures 1 and 2).
Notes:
3-Nitroso-3-halogen- bzw. 3-Nitroso-3-acyloxy-menthane 2 werden dargestellt. Ihre Isomerisierung zu den Diastereomeren 6 und die Substitution des Halogens werden untersucht. UV- und NMR-Spektren sowie CD-Kurven der 3-Nitroso-menthane 2 und 6 werden zu Aussagen über die Stereochemie benutzt (Tabb. 1-4, Abb. 1 und 2).
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.19717470118
