ISSN:
0009-2940
Keywords:
Silicon
;
Titanium
;
Diazadisilatitanacyclopentane
;
Aminodisilanes
;
Tetrachlorodisilanes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of two equivalents of N-trimethylsilylaniline (1) with two equivalents of n-butyllithium, followed by subsequent treatment with Si2Cl6 (2) leads to the formation of the tetrachlorodisilane RSiCl2SiCl2R (3) (R = PhNSiMe3). 3 is converted to RSi(NH2)2Si(NH2)2R (4) by reaction with liquid ammonia. 4 reacts with cp*TiMe3 (5) (cp* = η5-CsMe5) to yield the diazadisilatitanacyclopentane RSi(NH2)NHTiMe(cp*)NHSi(NH2)R (6). The crystal structure of 6 is reported.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971301213