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Chlorides and Acetylacetonates of Transition Metals as Catalysts for the Oxidation of 1-Indanol by Sodium Percarbonate (1997)

Aït-Mohand, Samia ; Muzart, Jacques ; Lunak, Stanislav

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1655-1658

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ISSN: 0009-2940

Keywords: Catalysis ; Oxidations ; Transition metals ; Sodium percarbonate ; 1, 2-Dichloroethane ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The screening of metal chlorides and metal acetylacetonates as catalysts for the oxidation of 1-indanol by sodium percarbonate (at reflux in 1,2-dichloroethane in the presence of small amounts of Adogen 464) has been carried out. The efficiency of the process depended on the nature of the transition metal and its oxidation state but, except for iron, was not greatly influenced by the nature of the ligands. Good conversions and yields have been obtained using PdCl2, RhCl3, RuCl3 and, particularly, MoO2(acac)2 as catalysts.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19971301116

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