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The Reactivity of Complexes of Nickel(0) and Platinum(0) Containing Benzyne and Related Small-Ring Alkynes (1997)

Bennett, Martin A. ; Wenger, Eric

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 1029-1042

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ISSN: 0009-2940

Keywords: Nickel ; Platinum ; Aryne complexes ; Cyclohexyne complexes ; Insertions ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The preparation and reactivities of cyclohexyne and aryne complexes of platinum(0) and nickel(0) are reviewed. These complexes undergo insertions with unsaturated molecules such as alkenes, alkynes, isocyanides, CO and CO2. In the case of the nickel- benzyne complexes, consecutive insertions are observed with alkynes, leading to substituted naphthalenes with good regioselectivities. A possible mechanism for these double insertions, based on a combination of steric and electronic factors, is discussed in detail.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19971300803

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