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The First Electron-Donor-Acceptor Paracyclophanes with Ferrocene NLO-Phores: Synthesis, Absorption and Electrochemical Properties (1997)

Kay, Kwang-Yol ; Baek, Yong Gu

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 581-584

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ISSN: 0009-2940

Keywords: Vinylferrocene ; Pd-catalyzed twofold and fourfold couplings ; Electron-donor-acceptor[2.2]paracyclophanes ; Charge transfer ; Cyclic voltammetry ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: As potential nonlinear optical material. 12-nitro-4,7-bis(2-ferrocenylvinyl)[2.2]paracyclophane (1) and 12-nitro-4,5,7,8-tetrakis(2-ferrocenylvinyl)[2.2]paracyclophane(2) have been synthesized by pd-catalyzed coupling reactions of vinylferrocene with the precursor cyclophanes 9 and 13, respectively. The absorption and electrochemical properties of 1 and 2 are also described.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19971300508

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