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Matrix-Isolation of Iodine Superoxide and Iodine Dioxide (1997)

Maier, Günther ; Bothur, Axel

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 130 (1997), S. 179-181

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ISSN: 0009-2940

Keywords: Matrix isolation ; Pyrolysis ; Photochemistry ; Iodine compounds ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Flash pyrolysis of a gas mixture containing iodine, oxygen and argon yields the hitherto unknown iodine superoxide, which can be identified by its UV absorption (λ max= 254 nm) after trapping the pyrolysate at 12 K. Irradiation converts iodine superoxide into iodine dioxide, identified by its IR and UV spectra.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19971300207

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