ISSN:
0009-2940
Keywords:
Monoterpenes
;
Sesquiterpenes
;
Stereoselectivity
;
Alk-l-enyllithium(sodium) Metal exchange, halogen vs. hydrogen
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(Z)-(3,3-Dimethylbicyclo[2.2.1]hept-2-ylidene)methyllithium can be readily generated by treatment of (Z)-3-bromomethylene-2,2-dimethylbicyclo[2.2.1]heptane with tert-butyl-lithium. At -75°C, the organometallic intermediate is configurationally stable and reacts with a variety of electrophiles under stereochemical retention.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300112