ISSN:
0009-2940
Keywords:
2-Isotetrasilanylsodium salt
;
Trisilylgermyl(alkali metal) salt
;
2-Methylisotetrasilane
;
Methyltrisilylgermane
;
Electron diffraction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis and Molecular Structure of CH3M(SiH3)3 (M=Si, Ge)A solution of 2-isotetrasilanylsodium (1a) was obtained in good yield from silane and sodium under special conditions. Methylation of 1a with methyl p1-toluenesulfonate yields 2-methylisotetrasilane (1b). The corresponding methyltrisilylgermane (2b) was synthesized via (K, Cs)Ge(SiH3)3 (2a) resulting from the reaction of cesium trichlorogermanide with KSiH3 followed by methylation. The molecular structures of 1a and 1b were determined by electron diffraction analyses.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260317
