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1,3,2-Diazaborinium-Verbindungen - neue Heteroaren-Kationen des Bors (1991)

Kuhn, Norbert ; Kuhn, Annette ; Lewandowski, Jörg ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 2197-2201

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ISSN: 0009-2940

Keywords: 1,3,2-Diazaborinium Compounds ; Calculations, AM1 ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: 1,3,2-Diazaborinium Compounds - New Cationic Boron HeteroarenesThe diazaborinium cation 9 is obtained by the reaction of the vinamidine boron chelate 8 with Et2O - BF3. The cyclic aluminium compound 13 forms with the dichloroboranes RBCl2 (R = Cl, Et, Ph) the cations 15,16a, and 16b. AM1 calculations demonstrate the π interaction of the boron with the nitrogen atoms as well as with the fluoro substituent.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19911241009

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