ISSN:
0009-2940
Keywords:
Titanium-nitrogen bonds
;
Dimer-monomer formation
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis and Structures of Imidotitanium Compounds - Directing the Monomer-Dimer Formation by Changing the Basicity of the SolventsThe reaction of (i-Pr)2PN(SiMe3)2 (1) with elemental sulfur leads to (i-Pr)2P(S)N(SiMe3)2 (2). Compound 2 reacts with TiCl4 with elimination of chlorotrimethylsilane to yield the adducts [(i-Pr)2P(S)NTiCl2-MeCN]2 (3) and (i-Pr)2P(S)N = TiCl2.3py (4), crystallized from MeCN or pyridine, respectively. Compound 3 crystallises in the space group Pbca, 4 in the space group p&1macr;.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240707