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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 753-756 
    ISSN: 0009-2940
    Keywords: Metal chelates ; Tetrachloroimidodiphosphates of Al, Ga, In, Sn, Ti ; Metallaheterocycles ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis of Imidodiphosphates of Aluminum, Gallium, Indium, Tin, and Titanium.Me3SiN[P(O)Cl2]2, (1) and Me3SnN[P(O)Cl2]2 (2) are synthesized from NaN[P(O)Cl2]2 and Me3SiCl or Me3SnCl, respectively. Treatment of 1 with AlCl3, GaCl3 InCl3, Me2SnCl2, and TiCl4 yields (3), (4), (5), (6), and (7), respectively. Reaction of LiN[P(O)Ph2]2 with TiCl4 leads to (8). NMR spectra demonstrate that the tetrachloroimidodiphosphate ligand coordinates through the oxygen atoms towards the metal atom.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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