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3-Alkylchinolizinium-iodide aus metalliertem α-Picolin und 3-Ethoxyacroleinen (1986)

Böhme, Roswitha ; Breitmaier, Eberhard

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 119 (1986), S. 2062-2065

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: 3-Alkylquinolizinium Iodides from Metalated α-Picoline and 3-Ethoxyacroleins2-Alkylquinolizinium iodides 4 are obtained in good overall yields by treating lithiated 2-methylpyridine 1 with 2-alkyl-3-ethoxyacroleins 2. 3-Alkyl-4-ethoxy-1-(2-pyridyl)-3-buten-2-ols 3 are isolated as primary products which readily cyclize to give the title compounds 4 upon heating in aqueous hydrogen iodide.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19861190627

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