ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of Alkali Metal Phosphides with White Phosphorus, II. Formation and Structure of 2-Lithio-2,3-dihydro-1,3-diphenyl-1H-benzotriphosphole2)The o-phenylenebis(lithium phosphide) 1 leads to a disproportionation of white phosphorus by formally taking up P+ and leaving P73-. The resultant title compound 2 may be converted to different derivatives 3 by reaction with electrophiles. According to a crystal structure analysis 2 (THF)3 consists of isolated ion pairs with Li singly coordinated to the central phosphorus.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19851180934