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Bis[bis(pentafluor-λ6-sulfanyl)amino]quecksilber, Hg[N(SF5)2]2 (1983)

Waterfeld, Alfred ; Mews, Rüdiger

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 116 (1983), S. 1674-1677

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Bis[bis(pentafluoro-λ6-sulfanyl)amino]mercury, Hg[N(SF5)2]2From the neat reaction of SF5NSF4 (1) and HgF2 at 20-60°C Hg[N(SF5)2]2 (8) was obtained in 50% yield. By 8 transfer of the bis(pentafluoro-λ6-sulfanyl)amino group is possible, from CH3I and CF3)SCl CH3N(SF5)2 (11) and CF3S—N(SF5)2 (12) were synthesized. A short comparison of the (SF5)2N with the (CF3)2N group is given.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19831160442

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