ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Transition Metal Thioketene Complexes, III. Synthesis and Structure of Thioketene Complexes from Hexacarbonylchromium, Hexacarbonyltungsten, and Tricarbonyl(cyclopentadienyl)manganeseStable dialkylthioketenes react photochemically with Cr(CO)6, W(CO)6, and (C5H5)Mn(CO)3 to give the complexes 2 and 3 with the ligand coordinated via the sulfur atom. The structure of the manganese complex 2c has been determined by X-ray diffraction.
Notes:
Stabile Dialkylthioketene (1a,b) reagieren photochemisch mit Cr(CO)6, W(CO)6 und (C5H5)Mn(CO)3 zu den Komplexen 2 und 3, in denen der Ligand über das Schwefelatom koordiniert ist. Die Struktur des Mangankomplexes 2c wurde röntgenographisch bestimmt.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19821150409