ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Iron Complexes as Model Compounds for the Homogeneous Hydrogenation of Carbon MonoxideThe μ-dinitrogen complex {Fe(CO)2[P(OCH3)3]2N2 (2) is prepared. Its reaction with H2, CH2O and C2H4 leads to dihydrido-, formaldehyde-, and ethylene-dicarbonylbis(trimethylphosphite)-iron complexes (4,5, and 6, respectively). The structures of 2 and of the dicarbonyltris(trimethylphosphite)iron complex 3 were determined by X-ray analyses.
Notes:
Der μ-Distickstoffkomplex {Fe(CO)2[P(OCH3)3]2N2 (2) wird dargestellt und mit H2, CH2O und C2H4 zu Dihydrido-, Formaldehyd- und Ethylen-dicarbonylbis(trimethylphosphit)eisen-Komplexen 4,5 bzw. 6 umgesetzt. Die Strukturen von 2 und dem Dicarbonyltris(trimethylphosphit)-eisen-Komplex 3 wurden röntgenographisch bestimmt.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19811140809
