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Über die Thermolyse von cis-und trans-1,3-Divinylcyclobutan (1981)

Schwarz, Wolfgang ; Trautmann, Walter ; Musso, Hans

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 114 (1981), S. 990-993

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Thermolysis of cis-and trans-1,3-DivinylcyclobutaneAt 300°C cis-1,3-Divinylcyclobutane (4) gives butadiene (5) and 4-vinyl-1-cyclohexene (6) as well as trans-1,3-divinylcyclobutane (2) in small quantity. 2 has been synthesized in an independent way and yields the same products as 4. The diradical 3 is considered as an intermediate.

Notes: cis-1,3-Divinylcyclobutan (4) reagiert um 300°C zu Butadien (5) und 4-Vinyl-1-cyclohexen (6), wobei trans-1,3-Divinylcyclobutan (2) in geringer Menge auftritt. 2 wird unabhängig hergestellt und liefert die gleichen Produkte sowie 4. Das Diradikal 3 wird als Zwischenstufe angesehen.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19811140317

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