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Bausteine von Oligosacchariden, XXV. Selektiver Abbau von Sisomicin zu Sisamin (1981)

Paulsen, Hans ; Janse, Rolf ; Stadler, Peter

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 114 (1981), S. 837-842

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Building Units for Oligosaccharides, XXV. Selective Degradation of Sisomicin to SisaminePeriodate oxidation of 1,2′,3,6′-tetra-N-acetylsisomicin (2) directly leads in high yield to tetra -N-acetylsisamine (16). At periodate splitting of 1 and 3 to 14 and 17 additional Barry-degradation seems to be favourable.

Notes: Periodatoxidation von 1,2′,3,6′-Tetra-N-acetylsisomicin (2) liefert in hohen Ausbeuten direkt Tetra-N-acetylsisamin (16). Bei der Periodatspaltung von 1 und 3 to 14 and 17 ist ein zusätzlicher Barry-Abbau zweckmäßig.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19811140302

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