Electronic Resource
Weinheim
:
Wiley-Blackwell
Berichte der deutschen chemischen Gesellschaft
112 (1979), S. 2342-2346
ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Basefree Wittig Reactions with Phase Transfer CatalytsKetones like trifluoroacetyl compounds - giving the haloform reaction in basic solutions - are able to react with mono or bis phosphonium fluorides without bases via Wittig reactions with very good yields. The phosphonium fluorides are prepared very easily from other phosphonium halides under phase transfer catalysis of crown ethers. The ratio of the stereoisomeric alkenes in the product and the spectra of the trans- respectively trans-trans alkenes are given.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19791120642
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