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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 112 (1979), S. 99-106 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal Sulfur Ylide Complexes, VII. η5-Thiacyclohexadienyl 1-Oxide as Novel Ligand in Complex AnionsFrom the reaction of syn-tricarbonyl(1-methyl-3,5-diphenylthiabenzene 1-oxide)chromium, molybdenum, and -tungsten (2a-c) with disodium tetracarbonylferrate or lithium diphenyl-phosphide the alkali salts of complex anions (3a-c, 5a-c) are obtained. They contain the novel ligand η5 -thiacyclohexadienyl 1-oxide. The alkali salts are converted into the tetraethylammonium salts 4a-c, which are characterized by analytical and spectroscopical data.
    Notes: Bei der Umsetzung von syn- Tricarbonyl(1-methyl-3,5-diphenylthiabenzol-1-oxid)chrom, -molybdän und-wolfram (2a-c) mit Dinatrium-tetracarbonylferrat oder Lithium-diphenylphosphid entstehen die Alkalisalze komplexer Anionen mit η5-Thiacyclohexadienyl-1-oxid als neuartigem Liganden (3a-c, 5a-c). Diese werden in die Tetraethylammoniumsalze 4a-c übergeführt und als solche auf analytischem und spektroskopischem Wege charakterisiert.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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