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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 109 (1976), S. 3034-3038 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Structural Isomerism of DimethylantimonytrichlorideThe vibrational spectra (i. r., Raman) of both dissolved and crystalline dimethylantimonytrichloride are recorded and assigned. The compound is monomeric in solution with symmetry C2v, it crystallizes as a dimeric, bridged by chlorine atoms and with methyl groups in trans-positions (symmetry D2h).
    Notes: Die Schwingungsspektren (IR, Raman) von gelöstem und Kristallisiertem Dimethylantimontrichlorid werden mitgeteilt und zugeordnet. Danach bildet die Verbindung in Lösung monomere Moleküle der trigonal-bipyramidalen Symmetrie C2v, während im kristallinen Zustand über Chlorobrücken verknüpfte Dimere mit zueinander trans-ständigen Methylgruppen der Symmetrie D2h vorliegen.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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