ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Investigation of Chromatographic Resolutions of Racemates, VI. Polymeric Amino Acid Derivatives as Optically Active AdsorbensStarting with optically active amino acids, the polyacrylamides 3a-h, 5a-d and 6a, b the polymethacrylamides 8a-c and the polyacrylic ester 6f were synthesized. The separation efficiencies of these polymers were determined by chromatography of racemic mandelic acid and mandelamide, respectively. The best separations of the enantiomers of both racemates were observed on the phenylalanine derivatives 3e and 5a.
Notes:
Die Polyacrylamide 3a-h, 5a-d und 6a, b die Polymethacrylamide 8a-c und der Polyacrylsäureester 6f wurden aus optisch aktiven Aminosäurederivaten hergestellt und auf ihre Trennwirkung durch Chromatographie racem. Mandelsäure sowie racem. Mandelamids geprüft. Die beste Trennung der Enantiomeren beider Racemate wurde an den Phenylalaninderivaten 3e und 5a beobachtet.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19761090601