ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Crystal and Molecular Structure of Bromo(3,8-diisopropyl-2,9-dimethyl-4,7-diaza-4,6-decadienyl-N, N′) nickel(II), a Square Planar Complex with a Tridentate N, N, C-ChelateThe title compound crystallizes monoclinically in the space group P21/a with a = 14.654 Å, b = 11.333 Å, c = 11.664 Å, β = 92.51° and 4 formula units. THe structure of the complex is characterized by a square planar coordination for the nickel atom with the ligand atoms Br, N, N,C. The bond distances are Ni—Br = 2.302 Å, Ni—N = 1.995 and 1.820 Å, and Ni—C = 1.907 Å. The details of the structure are discussed.
Notes:
Die Titelverbindung kristallisiert monoklin in der Raumgruppe P21/a mit a=14.654 Å, b = 11.333 Å, c =11.664 Å, β = 92.51° und 4 Formeleinheiten. Die Struktur des Komplexes ist durch eine planar-quadratische Nickel-Koordination mit den Ligandenatomen Br,N,N,C ausgezeichnet. Die Bindungsabstände betragen Ni—Br = 2.302 Å, Ni—N = 1.995 bzw. 1.820 Å und Ni—C = 1.907 Å. Die Einzelheiten der Strukture werden diskutiert.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19761090509
