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The Bucherer Reaction and the Preparative Use of its Intermediate ProductsDedicated to Professor A. Rieche on the occasion of his 65th birthday (1967)

Seeboth, H.

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 6 (1967), S. 307-317

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ISSN: 0570-0833

Keywords: Bucherer reaction ; Naphthalene sulfonic acids ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The study of purified intermediate products of the Bucherer reaction has shown that this reaction proceeds, not via bisulfite addition compounds of the keto form of the naphthols and the ketimine form of the naphthylamines, but via tetralonesulfonic acids and tetraloniminesulfonic acids. The intermediates lead to compounds that are otherwise difficult or impossible to obtain, and some of which are new. The mechanism of the Bucherer reaction is discussed in detail.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/anie.196703071

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