ISSN:
0570-0833
Keywords:
Trichloropyrimidyl dyes
;
Dyes/Pigments
;
Dichloropyrimidyl dyes
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Several examples are used to show that the reactivity of dichloro- and trichloropyrimidyl dyes and the sensitivity of their dyeings to hydrolysis are determined by the nature of the bridge unit between the chromophore and the reactive system. The tendency of the dyeings to hydrolyze in acid and, more particularly, in alkaline media increases with increasing reactivity of the dyes. In alkaline media, dyeings made with dyes containing oxygen bridges are cleaved mainly between the reactive system and the chromophore, while in dyeings made with dyes containing imino or methylimino bridges, the linkage between the reactive system and the cellulose is hydrolyzed.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196205681