ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
In industrial polymer processing, polymeric melts give rise to shear stresses above 105 dynes/cm2. For the determination of rheological properties and particularly melt elasticity, only the capillary type instrument is applicable to this range. In this paper, a comparative experimental study of the first normal stress difference, obtained from end pressure losses, entrance pressure losses and die swell is reported for polystyrene and high impact polystyrene. Good agreement between results from the three methods of measurement was obtained. The results are in accordance with literature data obtained using a capillary rheometer. It is seen that the values of first normal stress difference are greater in polystyrene than in high impact polystyrene.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760210509