ISSN:
0947-5117
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Description / Table of Contents:
Some chemical properties of tetrachloroethylene, trichloroethylene 1.1.1-trichloroethane - An overviewA review is presented on the liquid phase decomposition reactions of tetrachloroethylene, trichloroethylene, trichloroethylene and 1,1,1-trichloroethane. Emphasis is placed on those reactions - like oxidative breakdown, thermolysis, hydrolysis - which are of interest for the corrosion of metals in the aforementioned chlorohydrocarbons. Tri- and tetrachloroethylene are susceptible to oxidative breakdown, whereas 1,1,1-trichloroethane shows appreciable hydrolysis.
Notes:
Die möglichen Zersetzungsreaktionen des Tetrachlorethylens, Trichlorethylens und 1,1,1-Trichlorethans in flüssiger Phase werden vorgestellt. Es werden insbesondere solche Reaktionen besprochen - wie die oxidative Zersetzung, Thermolyse und Hydrolyse -, die für die Korrosion von Metallen in den o. a. Halogenkohlenwasserstoffen von Interesse sind. Trichlorethylen und Perchlorethylen sind empfindlich gegenüber oxidativem Abbau, während 1,1,1-Trichlorethan zur Hydrolyse neigt.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/maco.19800310303
