ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
This article completes the analysis of high-temperature mutual solubilities of hydrocarbons and water. Part I (Tsonopoulos and Wilson, 1983) presented benzene, cyclohexane, and n-hexane, while Part II (Heidman et al., 1985) extended the investigation to ethylbenzene, ethylcyclohexane, and n-octane. Part III presents experimental data up to the three-phase critical end point for C6, C8, and C10 1-alkenes, n-decane, n-butylcyclohexane, m-diethylbenzene, p-diisopropylbenzene, cis-decalin, tetralin, 1-methylnaphthalene, and 1-ethylnaphthalene. The thermodynamic analysis of Henry's constants for hydrocarbons in water is extended to the critical temperature of water, while the solubility and volatility of water in hydrocarbons are successfully correlated with several modifications of the Redlich-Kwong equation of state.
Additional Material:
13 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690430226
