ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Using the Karman-Pohlhausen integral method, an analysis has been made for turbulent flow on a rotating hemispherical electrode mounted on an inert support rod of equal radius. The resulting friction coefficient is then substituted into the Chilton-Colburn relation to give a rate equation for mass transfer at high Schmidt numbers. Experiments with a diffusion-controlled electrolytic system over a range of Sc from 910 to 6,300 confirm the validity of the theory for Re 〉 40,000. A comparison with the results of previous heat and mass transfer measurements reveals that the turbulent flow on the present geometry is different from that on a rotating sphere and on a hemispherical electrode mounted on a support rod of larger radius.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690200206