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Free volume theory for viscosity of simple nonpolar liquids. Part I. Pure components (1969)

Gubbins, Keith E. ; Tham, M. J.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 15 (1969), S. 264-269

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: An improved free volume theory is presented, and is shown to predict the variation of viscosity with temperature and pressure satisfactorily for liquids composed of simple, nonpolar molecules, when the density is greater than twice the critical value. Allowance is made for the temperature dependence of the minimum free volume for a jump, and for the density dependence of the activation energy at constant volume. Corresponding states relationships are provided for these quantities, the reducing parameters being the temperature and molal volum at the melting point.

Additional Material: 7 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690150225

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