ISSN:
0749-1581
Keywords:
(E)-Azobenzene
;
2,2′-Dimethyl-(E)-azobenzene
;
Radical anions
;
ESR
;
ENDOR
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The radical anion of (E)-azobenzene, generated from the neutral compound by reaction with potassium mirror in an ethereal solvent, has been fully characterized by its hyperfine data with the use of ESR, ENDOR and TRIPLE-resonance spectroscopy. Assignments of coupling constants to protons in the individual positions are based on comparison with the spectra of the radical anions of 4,4′-dideuterio and 2,2′-dimethyl derivatives. Effects of 14N hyperfine anisotropy on ESR spectra and of association with the counter ion K+ are briefly discussed.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260290715
