ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Experimental solvent effects on 13C and 17O chemical shifts of acetone, and 13C chemical shifts of acetonitrile are compared with theoretical calculations by Jallali-Heravi and Webb (solvaton model). Calculated values are, generally, in agreement with experimental results for atoms belonging to polar groups, but not for methyl carbons for which van der Waals interaction effects are predominant.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270160319