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A 13C NMR study of pyridine in the presence of aqueous solutions of carbohydrates (1981)

Hall, Laurance D. ; Yalpani, Mansur

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 16 (1981), S. 60-62

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ISSN: 0030-4921

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Spin-lattice relaxation rates of the 13C responses of pyridine were measured in the presence of aqueous sucrose and sodium alginate solutions and calcium alginate gels. In each case the results indicated a reduction in the overall tumbling rate of pyridine compared with that in aqueous media due to molecular association with the carbohydrate. Although anisotropic motion about the C-4:N axis of pyridine was apparent in the sucrose solutions no consistent trends were observed for the alginate samples.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1270160116

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