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Xenon as a mobile phase in supercritical fluid chromatography (1991)

Raynor, Mark W. ; Shilstone, Gavin F. ; Clifford, Anthony A. ; [et al.]

New York, NY [u.a.] : Wiley-Blackwell

Journal of Microcolumn Separations 3 (1991), S. 337-347

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ISSN: 1040-7685

Keywords: supercritical fluid chromatography ; mobile phases ; xenon ; SFC-FTIR ; polynuclear aromatic hydrocarbons ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Supercritical xenon and CO2 are compared as solvents by means of solubilities (calculated by means of the Peng-Robinson equation of state) and chromatographic behavior for some polynuclear aromatic hydrocarbons; reasons for the apparent superiority of xenon are discussed. The advantages of the use of xenon as a mobile phase in coupled supercritical fluid chromatography-Fourier transform infrared spectrometry are evaluated from analyses of monomer and oligomer mixtures.

Additional Material: 13 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mcs.1220030408

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